By Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, Phil N. Ross
With contributions from a world staff of professional authors, this ebook comprises the most recent developments in tailoring interfacial houses electrochemically. The chapters hide a variety of natural and inorganic compounds, with purposes starting from electrochemistry to nanotechnology and biology.
Of curiosity to actual, floor and electrochemists, fabrics scientists and physicists.
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Extra resources for Chemically Modified Electrodes (Advances in Electrochemical Sciences and Engineering)
4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules interferences from oxygen and ascorbic acid with this enzyme electrode provides strong support for the notion that efﬁcient direct electron transfer to enzymes such as glucose oxidase could solve many of the problems associated with diffusing redox species shuttling electrons between the enzyme and the electrode. Other workers have also demonstrated fast electron transfer to enzymes using nanoparticle assemblies but typically these electrodes have employed enzymes with redox-active centers close to the exterior of the protein.
This deposition process was repeated 4 times to form the ﬁnal electrode to detect ethanol vapors. 16). In normal air, the SnO2 can adsorb oxygen species of O2À, OÀ and O2À on the surface, which increased the resistance of the SnO2 nanostructured ﬁlm . Sensing of ethanol vapors was completed in a 300 C environment. 16 TEM images of SnO2 ordered porous films on the external surface of a glass tube. (Reprinted with permission from Ref. . Ó 2005 Wiley-VCH Verlag GmbH & Co. 3 Catalytic Properties the oxygen from the surface, and as a result decreases the resistance in the ﬁlm.
The surfactant octaethyleneglycol monohexadecyl ether was ﬁrst used to form a hexagonal mesophase, which was stable at room temperature. In the continuous water phase hexachloroplatinic acid was dissolved. A large piece (>3 mm) of a less-noble metal (Fe, Zn Mg) was placed into the liquid crystal, which reduced the platinum precursor. The mixture turned black when the reaction was left to stand at room temperature for 24 h. 5 m2 gÀ1. 15 TEM image of Pt nanoparticles that have been produced by lyotropic liquid crystal templating.